Saturday, August 8, 2026

Solutions and Concentration UPCAT Reviewer: Lesson and Practice

TEACHER ABI UPCAT SCIENCE

Solutions and Concentration

Identify true solutions, distinguish rate from solubility, calculate concentration, and predict dilution, evaporation, and crystallization.

5-10 minute lesson27 original questionsAdaptive practiceSaves progress
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Solutions and Concentration

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A solution is homogeneous; concentration tells how much solute is present relative to the mixture

A solution contains solute particles uniformly dispersed in a solvent. The label (aq) means a substance is dissolved in water; it does not mean the pure substance is a liquid.

mass percent = mass solute / mass solution × 100%molarity M = moles solute / liters solutiondilution: M₁V₁ = M₂V₂

An unsaturated solution can dissolve more solute. A saturated solution has reached its equilibrium solubility under the stated conditions. Undissolved excess does not increase the dissolved concentration.

Rate and solubility are not the same

Stirring and crushing commonly increase how fast a solid dissolves. They do not necessarily change the maximum amount that can dissolve at equilibrium.

Track solute amount during dilution or evaporation

Adding solvent lowers concentration if solute is unchanged. Removing solvent raises concentration until saturation may cause crystallization.

DO IT FAST

Read the phase label before using chemical intuition

(aq): dissolved in water—a homogeneous aqueous solution.

(s): solid.

(l): pure liquid phase.

(g): gas.

For dilution, the number of moles of solute stays constant, so use M₁V₁ = M₂V₂.

Why it works

The phase label resolves official-style identification questions immediately and prevents a pure liquid or solid from being mistaken for an aqueous solution.

WORKED EXAMPLES

Five forms you should recognize

1. Recognize an aqueous solution

Problem: Which sample is a substance dissolved in water: KOH(aq), NaCl(s), HCl(g), or H₂O(l)?

Recognize: The phase label tells the physical condition. Only (aq) explicitly means “dissolved in water.”

Answer: KOH(aq) is the aqueous solution. NaCl(s) is a solid, HCl(g) is a gas, and H₂O(l) is pure liquid water—not a solute dissolved in water.

2. Find mass percent

Problem: A student dissolves 10 g of salt in 90 g of water. What percent by mass of the final solution is salt?

Recognize: The denominator is the total solution mass, not the water mass alone.

mass solution = 10 g + 90 g = 100 gmass percent = 10/100 × 100% = 10%

Answer: The solution is 10% salt by mass.

3. Calculate molarity

Problem: A laboratory solution contains 0.50 mol of glucose in a final solution volume of 2.0 L. What is its molarity?

Recognize: Molarity means moles of solute per liter of solution.

M = 0.50 mol / 2.0 L = 0.25 M

Answer: The glucose concentration is 0.25 M.

4. Prepare a dilution

Problem: A student needs 100 mL of 0.50 M solution using a 2.0 M stock solution. What volume of stock should be measured before adding water to a final volume of 100 mL?

Recognize: Dilution changes volume and concentration but not the moles of solute taken from the stock.

M₁V₁ = M₂V₂2.0(V₁) = 0.50(100 mL)V₁ = 25 mL

Answer: Measure 25 mL of stock, then add water until the total volume reaches 100 mL.

5. Predict crystallization on cooling

Problem: At 80°C, 50 g of a salt can dissolve in 100 g of water. At 20°C, only 30 g can remain dissolved. A saturated solution containing 50 g of dissolved salt is cooled from 80°C to 20°C. What happens?

Recognize: Cooling lowers this salt’s solubility, so the cooler water cannot keep all 50 g dissolved.

mass crystallized = 50 g − 30 g = 20 g

Answer: About 20 g crystallizes, while 30 g remains dissolved.

COMMON TRAPS

Check before you commit

  • Treating every liquid sample as a solution
  • Reading (l) as dissolved in water
  • Using solvent volume instead of final solution volume for molarity
  • Saying stirring always increases final solubility
  • Forgetting to convert milliliters to liters
  • Assuming gas solubility increases with temperature
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QUICK ANSWERS

Solutions and Concentration FAQ

Can a solution contain a gas or solid solvent?

Yes. Solutions may occur in different phases; air and metal alloys are common examples.

Does a saturated solution always have visible solid?

Not necessarily. It is at the solubility limit; visible solid appears when excess solute is present.

Why does opening a soft drink cause fizzing?

Lower pressure above the liquid reduces carbon-dioxide solubility, so dissolved gas escapes.

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